Zirconium (IV) chloride

Zirconium (IV) chloride, kuj hu uazirconium tetrachloride, muaj cov mis molecular ZrCl4 thiab molecular hnyav ntawm 233.04.Feem ntau yog siv los ua cov tshuaj analytical reagents, organic synthesis catalysts, waterproofing agents, tanning agents

Khoom npe:Zirconium chlorideZirconium tetrachloride;Zirconium (IV) chloride

Molecular Luj: 233.04

PIB: 233-058-2

Boiling point: 331 (sublimation)

Qhov ceev: 2.8

Tshuaj formula:ZrCl4

CAS:10026-11-6

Melting point: 437

Dej solubility: Soluble hauv dej txias

1. Khoom

Lub cev thiab tshuaj muaj zog

1. Cim: Dawb glossy siv lead ua los yog hmoov, yooj yim deliquescent.

2. Melting point (℃): 437 (2533.3kPa)

3. Boiling point (℃): 331 (sublimation)

4. Cov txheeb ze ntom ntom (dej=1): 2.80

5. Saturated vapor siab (kPa): 0.13 (190 ℃)

6. Lub siab tseem ceeb (MPa): 5.77

7. Solubility: Soluble nyob rau hauv dej txias, ethanol, thiab ether, insoluble nyob rau hauv benzene, carbon tetrachloride, thiab carbon disulfide.

Ib qho yooj yim kom nqus dej noo thiab noo noo, hydrolyzed rau hauv hydrogen chloride thiab zirconium oxychloride hauv cov huab cua ntub lossis dej aqueous, qhov sib npaug yog raws li nram no:

Kev ruaj ntseg

1. Stability: ruaj khov

2. Cov tshuaj txwv tsis pub muaj: dej, amines, cawv, acids, esters, ketones

3. Cov xwm txheej kom tsis txhob sib cuag: huab cua ntub

4. Polymerization txaus ntshai: tsis yog polymerization

5. Decomposition khoom: chloride

2.Aplication

(1) Siv los ua hlau zirconium, pigments, textile waterproofing agents, tawv tanning agents, thiab lwm yam.

(2) Siv rau zus tau tej cov zirconium tebchaw thiab cov organic hlau organic tebchaw, nws yuav siv tau raws li ib tug hnyav thiab ib tug purifying tus neeg saib xyuas rau remelted magnesium hlau, nrog rau kev tshem tawm cov hlau thiab silicon.

3.Synthetic method

Ntsuas zirconia thiab calcined carbon dub raws li molar piv ntawm kev ntsuas, sib tov sib npaug thiab muab tso rau hauv lub nkoj plooj (porcelain).Muab lub nkoj plooj (porcelain) tso rau hauv lub raj plooj (porcelain tube) thiab ua kom sov rau 500 ℃ hauv cov roj chlorine rau calcination.Sau cov khoom siv lub ntxiab ntawm chav tsev kub.Xav txog qhov sublimation ntawm zirconium tetrachloride ntawm 331 ℃, 600 hli ntev raj tuaj yeem siv los ua sublimate nws hauv cov dej hydrogen ntawm 300-350 ℃ kom tshem tawm oxides thiab ferric chloride hauv zirconium chloride.

4. Kev cuam tshuam rau ib puag ncig

Kev phom sij

Invasion route: inhalation, noj, tiv tauj daim tawv nqaij.

Kev phom sij rau kev noj qab haus huv: Kev nqus pa tuaj yeem ua rau ua pa ua pa, tsis txhob nqos.Nws muaj zog khaus thiab tuaj yeem ua rau tawv nqaij kub hnyiab thiab qhov muag puas.Kev tswj ntawm qhov ncauj tuaj yeem ua rau kub hnyiab hauv qhov ncauj thiab caj pas, xeev siab, ntuav, quav dej, quav ntshav, ntuav, thiab ntuav.

Cov teebmeem ntev: Ua rau daim tawv nqaij granuloma.Mob me me rau txoj kev ua pa.

 Toxicology thiab ib puag ncig

Mob toxicity: LD501688mg/kg (kev tswj qhov ncauj rau nas);665mg / kg (mus rau qhov ncauj)

Cov yam ntxwv muaj kev phom sij: Thaum raug cua sov lossis dej, nws decomposes thiab tso tawm cua sov, tso cov pa phem thiab corrosive.

Combustion (decomposition) khoom: hydrogen chloride.

Laboratory soj ntsuam txoj kev: Plasma spectroscopy (NIOSH txoj kev 7300)

Kev txiav txim siab hauv huab cua: sau cov qauv nrog lub lim, yaj nws nrog cov kua qaub, thiab tom qab ntawd ntsuas nws nrog atomic absorption spectroscopy.

Environmental standards: Occupational Safety and Health Administration (1974), Air Time Weighted Average 5.

Leakage teb thaum muaj xwm ceev

Cais tawm qhov chaw paug paug, teeb tsa cov cim ceeb toom nyob ib puag ncig nws, thiab qhia cov neeg ua haujlwm kho mob xwm txheej ceev kom hnav lub npog ntsej muag roj thiab cov khaub ncaws tiv thaiv tshuaj.Tsis txhob nkag mus rau hauv cov khoom xau ncaj qha, zam cov plua plav, ua tib zoo cheb nws, npaj cov tshuaj txog li 5% dej lossis kua qaub, maj mam ntxiv cov dej ammonia kom txog thaum nag lossis daus tshwm sim, thiab tom qab ntawd muab pov tseg.Koj tuaj yeem yaug nrog dej ntau, thiab dilute cov dej ntxuav rau hauv cov dej khib nyiab.Yog tias muaj ntau qhov dej ntws tawm, tshem tawm raws li kev taw qhia ntawm cov neeg ua haujlwm.Txoj kev pov tseg pov tseg: Sib tov cov khib nyiab nrog sodium bicarbonate, tshuaj tsuag nrog dej ammonia, thiab ntxiv dej khov.Tom qab cov tshuaj tiv thaiv nres, yaug nrog dej rau hauv lub kav dej.

 Kev tiv thaiv

Kev tiv thaiv ua pa: Thaum raug plua plav, yuav tsum hnav lub npog ntsej muag roj.Hnav ib lub tshuab ua pa uas muaj tus kheej thaum tsim nyog.

Kev tiv thaiv qhov muag: Hnav cov tsom iav tiv thaiv tshuaj lom neeg.

Cov khaub ncaws tiv thaiv: Hnav khaub ncaws ua haujlwm (ua los ntawm cov khoom siv tiv thaiv corrosion).

Kev tiv thaiv tes: Hnav hnab looj tes roj hmab.

Lwm yam: Tom qab ua haujlwm, da dej thiab hloov khaub ncaws.Khaws cov khaub ncaws uas muaj co toxins cais tawm thiab rov siv dua tom qab ntxuav.Ua tib zoo saib xyuas tus cwj pwm zoo.

 Kev pab thawj zaug

Kev sib cuag ntawm daim tawv nqaij: Tam sim ntawd yaug nrog dej tsawg kawg 15 feeb.Yog tias kub hnyiab, nrhiav kev kho mob.

Kev sib cuag ntawm qhov muag: Tam sim ntawd rub daim tawv muag thiab yaug nrog dej ntws los yog physiological saline rau tsawg kawg 15 feeb.

Inhalation: Tshem tawm sai sai ntawm qhov chaw mus rau qhov chaw uas muaj huab cua ntshiab.Ua pa ua pa uas tsis muaj kev cuam tshuam.Ua pa ua pa yog tsim nyog.Nrhiav kev kho mob.

Kev Noj Qab Haus Huv: Thaum tus neeg mob tsaug zog, yaug lub qhov ncauj tam sim ntawd, tsis txhob ntuav ntuav, thiab haus mis nyuj lossis qe dawb.Nrhiav kev kho mob.

Txoj kev tua hluav taws: ua npuas ncauj, carbon dioxide, xuab zeb, hmoov qhuav.

5. Cia txoj kev

Khaws rau hauv qhov chaw txias, qhuav, thiab zoo ventilated warehouse.Khaws kom deb ntawm qhov hluav taws kub thiab qhov chaw kub.Lub ntim yuav tsum raug kaw thiab tiv thaiv los ntawm noo noo.Nws yuav tsum tau muab cais tawm ntawm cov kua qaub, amines, cawv, esters, thiab lwm yam, thiab tsis txhob sib tov cia.Lub chaw cia khoom yuav tsum tau nruab nrog cov ntaub ntawv tsim nyog kom muaj cov xau.

6 kev suav chemistry Data Editing

1. Tus nqi siv rau hydrophobic parameter xam (XlogP): Tsis yog

2. Tus naj npawb ntawm cov nyiaj pub dawb hydrogen: 0

3. Tus naj npawb ntawm hydrogen bond receptors: 0

4. Number of rotatable chemical bond: 0

5. Tus naj npawb ntawm tautomers: Tsis muaj

6. Topological molecule polarity nto thaj tsam: 0

7. Tus naj npawb ntawm cov atom hnyav: 5

8. Nto nqi: 0

9. Kev nyuaj siab: 19.1

10. Tus lej ntawm Isotope Atoms: 0

11. Txiav txim seb tus naj npawb ntawm atomic qauv chaw: 0

12. Tus naj npawb ntawm cov chaw tsim kho atomic tsis paub tseeb: 0

13. Txiav txim seb tus naj npawb ntawm cov chaw tso tshuaj stereo: 0

14. Tus naj npawb ntawm cov tshuaj tsis paub tseeb stereocenters: 0

15. Number of covalent bond units: 1